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Toxic Tuesdays

Nitrates

Toxic Tuesdays

CHEJ highlights several toxic chemicals and the communities fighting to keep their citizens safe from harm.

Nitrates

Nitrates are a class of compounds that contain nitrogen. They can occur naturally in air, water, and soil, and living things need them to survive. Nitrates are used for industrial purposes to make fertilizers, ammunition, and explosives. They are also used to preserve food, most commonly in the process of curing meat. Many vegetables we eat are naturally rich in nitrates as well.

When nitrate-containing fertilizers are used on crops or yards, the nitrates can easily migrate into surface water and groundwater. This means that people who work with these fertilizers or live near where they are applied could be exposed to nitrates in their drinking water. For most of the population, nitrate exposure happens through the food we eat. The amount of nitrates consumed in a normal diet is generally considered safe, and much of the nitrates our bodies ingest or make naturally are excreted every day. However, people may be exposed to high levels of nitrates by eating lots of foods rich in nitrates such as spinach, lettuce, cured meat, processed meat, fish, and beer.

Once consumed, the body can convert nitrates into similar compounds called nitrites. High levels of nitrites can decrease the blood’s ability to carry oxygen to our cells. This can cause dizziness, headaches, cramps, vomiting, decreased blood pressure, increased heart rate, and death. Infants seem to be more sensitive to the health effects of nitrite exposure than adults.

Once nitrates get converted into nitrites in the body, they can be further converted into compounds called nitrosamines, which are known to cause cancer. For this reason, the International Agency for Research on Cancer has determined that ingesting nitrates probably causes cancer in humans. Because nitrates occur in nature and are made naturally by our bodies, it can be hard to know our exposure risk from dietary and industrial sources. This makes it particularly important for the federal government to regulate nitrates from sources such as fertilizers and food preservation in order to keep people safe from the adverse health effects of exposure.

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A year of fear and distrust in Dukeville

unknownDUKEVILLE, North Carolina — Deborah Graham’s life changed on April 18, 2015, with the arrival of a letter.
Graham was in the kitchen, pouring a cup of coffee. Her husband, Marcelle, opened a large certified envelope just dropped off by the mail carrier.
“The North Carolina Division of Public Health recommends that your well water not be used for drinking and cooking,” the letter said.
“What did you just say?” Graham asked, incredulous.
“The water’s contaminated,” her husband replied.
Graham’s eyes flew to her kitchen faucet. She thought about the coffee she’d just swallowed. The food she’d cooked and sent over to her church. The two children she’d raised in this house.
She dumped the rest of her coffee down the sink.
The ordinary routines of the Graham household had been disrupted by vanadium, which can cause nausea, diarrhea and cramps. In animal studies, vanadium has caused decreased red blood cell counts, elevated blood pressure and neurological effects.
While the element is found in Earth’s crust, it’s also one of several metals found in coal ash—the toxic leftover waste from burning coal.
State officials had discovered vanadium in the Graham’s well water at an estimated concentration of 14 parts per billion, more than 45 times the state screening level of 0.3 ppb—a threshold set by health officials to warn well owners of potential risks.
And the Grahams weren’t alone. Laboratory tests showed 74 wells in the tiny Dukeville community in Salisbury, North Carolina, exceeded state or federal thresholds. Across the state, 424 households received similar do-not-drink notifications, Department of Environmental Quality Assistant Secretary Tom Reeder said in January.
Most letters cited either vanadium or hexavalent chromium, the chemical compound made famous by activist Erin Brockovich, who discovered it had tainted water in Hinkley, California. Hexavalent chromium is carcinogenic when inhaled or swallowed in drinking water, and another metal often found in coal ash.
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